In the present study, the effect of size distribution of magnetite nanoparticles in a PVDF matrix on the magnetic propertiesof PVDF? Fe3O4 nanocomposites was experimentally and theoretically investigated. The size distribution of nanoparticlesin polymer matrix and morphology of the nanocomposites were studied by the means of scanning electron microscopyand atomic force microscopy. It was found that when the Fe3O4 nanoparticles are introduced into the polymermatrix, their coagulation takes place. The increase in the size of the particles depends on their concentration in the polymermatrix, the type of polymer (polar, non-polar, its viscosity, etc. ), reaction temperatures, etc. In addition, when Fe3O4nanoparticles are introduced into the polymer network, the oxidation of the surface layer of particles occurs and themagnetic size decreases. Consequently, the reduced magnetic properties may also be observed. The hysteresis loops havebeen recorded in small magnetic field range. It was found that the magnetic hysteresis parameters depend on the size andconcentration of Fe3O4 nanoparticles. Theoretical calculations were compared with experimental results obtained fromM(H) measurements. The reasons of differences between theoretical and experimental results have been explained.